Published February 1978
| Version v1
Journal article
Molecular and electronic structure of heteropolycomplexes
Description
Valent zones of heteropolyanions SiMo11VO406-, SiMo12O404-, SiW12O404- and their reduced forms have been studied. In X-ray electron spectra of the reduced forms one main peak is observed at 7.2 eV caused by 2p-orbitals of oxygen atoms and shoulders on a low-energy side which are shifted towards lower energy values when passing from V to Mo and W
Additional details
Additional titles
- Subtitle (English)
- Communication 5. X-ray electron study of mixed valence heteropolyanions SiMsub(12-x)Msub(x)sup(1)Osub(40)
- Original title (Russian)
- Молекулярное и электронное строение гетерополикомплексов
- Original subtitle (Russian)
- Soobshchenie 5. Rentgenoehlektronnoe issledovanie smeshanovalentnykh geteropolianionov SiMsub(12-x)Msub(xsup(1)Osub(40).
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Ser. Khim.
- Journal Issue
- no.2
- Series
- Izv. Akad. Nauk SSSR, Ser. Khim.
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 9407077
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ELECTRON SPECTRA; ELECTRONIC STRUCTURE; ENERGY; HETEROPOLYANIONS; MOLYBDENUM COMPLEXES; SILICON COMPLEXES; TUNGSTEN COMPLEXES; VALENCE; VANADIUM COMPLEXES; X-RAY SPECTRA
- Descriptors DEC
- ANIONS; CHARGED PARTICLES; COMPLEXES; IONS; SPECTRA; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- For English translation see the journal Bull. Acad. Sci. USSR, Div. Chem. Sci.