Published June 1993
| Version v1
Journal article
Intrasphere redox transformations in platinum complexes: a model of single-electron process and consequences from the model
- 1. Leningradskij Tekhnologicheskij Inst., Leningrad (Russian Federation)
Description
Consideration is given to single-electron oxidation of plane-square Pt(2) compounds to octahedral Pt(3) complexes, and to consequences from the model. Phenomenon of trans-elimination of ligands from Pt(2) complexes under their oxidation by cerium in particular is explained. A series of trans-effect for Pt(3) compounds, based on the value of potentials of single-electron ligand oxidation was obtained
Additional details
Additional titles
- Original title (Russian)
- Внутрисферные окислительно-восстановительные превращения в комплексах платины: модель одноэлектронного процесса и следствия из нее
Publishing Information
- Journal Title
- Koordinatsionnaya Khimiya
- Journal Volume
- 19
- Journal Issue
- 6
- Journal Page Range
- p. 411-419.
- ISSN
- 0132-344X
- CODEN
- KOKHDC
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 25038665
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CERIUM COMPOUNDS; LIGANDS; MOLECULAR STRUCTURE; OXIDATION; PLATINUM COMPLEXES; REDUCTION; REVIEWS
- Descriptors DEC
- CHEMICAL REACTIONS; COMPLEXES; DOCUMENT TYPES; RARE EARTH COMPOUNDS; TRANSITION ELEMENT COMPLEXES