Published September 25, 2024 | Version v1
Journal article

Wave vector dependence of x-ray beam induced dynamics in sodium silicate glasses

  • 1. Department of Physics, University of Trento, 38123 Povo, Trento, Italy
  • 2. Van der Waals-Zeeman Institute, Institute of Physics, University of Amsterdam, 1098XH Amsterdam, The Netherlands
  • 3. Faculty of Science, Université libre de Bruxelles, Bd de la Plaine 2, 1050 Ixelles, Belgium
  • 4. Laboratoire Charles Coulomb, Université de Montpellier, CNRS, Pl. Eugéne Bataillon, 34095 Montpellier, France
  • 5. Department of Physics and Astronomy 'Galileo Galilei', University of Padova, 35131 Padova, Italy
  • 6. Hasylab at DESY, Notkestraße 85, D-22607 Hamburg, Germany

Description

We have probed the atomic dynamics of two sodium silicate glasses in a wide wave vector range by means of x-ray photon correlation spectroscopy. The wide angle setup has been modified to cover a Q range that extends to small angles, close to the range normally covered by the usual small-angle x-ray scattering configuration. During irradiation, the oxide samples undergo a transformation to a new amorphous state with different structural and dynamical properties. The observed dynamics before and after the structural transformation shows the presence of de Gennes narrowing. In the low wave vector region, the dynamics is affected by a ballisticlike motion at low absorbed doses, while the glass obtained after prolonged irradiation has a Q-independent relaxation time. This observation strengthens the interpretation of the new amorphous phase as a rejuvenated glass that lies in a higher-energy region of the potential landscape.

Additional details

Identifiers

DOI
10.1103/PhysRevB.110.094207;
Crossref Funder ID
10.13039/501100001647; 10.13039/501100009318; 10.13039/100017150; 10.13039/100010661;

Publishing Information

Journal Title
Physical Review B
Journal Volume
110
Journal Issue
9
Journal Page Range
9 pgs.
ISSN
1550-235X

Optional Information

Copyright
©2024 American Physical Society
Contract/Grant/Project number
730872
Notes
Contact Email: Contact author: erica.alfinelli@unitn.it; Contact Email: Contact author: giacomo.baldi@unitn.it; Record automatically processed
Funding organization
Deutsches Elektronen-Synchrotron; Helmholtz Association; CALIPSOplus; Horizon 2020 Framework Programme