Published 1987 | Version v1
Journal article Metadata-only

Liquid-liquid extraction of trivalent actinides and lanthanides with 1-phenyl-3-methyl-4-trifluoroacetyl pyrazolone-5

Creators

  • 1. Bhabha Atomic Research Centre, Bombay (India). Radiochemistry Div.

Description

Extraction of the trivalent actinides Am, Cm and Cf and lanthanides Eu, Tb, Tm and Lu has been studied with 1-phenyl-3-methyl-4-trifluoroacetyl pyrazolone-5(HPMTFP) in chloroform and benzene. The formation of a self-adduct species M(PMTFP)3· HPMTFP has been observed with Am, Cm and Eu but only the chelate species M(PMTFP)3 with Cf, Tb, Tm and Lu. The reasons for the formation of a self-adduct species with lighter actinides and lanthanides and not with the heavier ones of the pyrazolones have been discussed. (author)

Additional details

Publishing Information

Journal Title
Polyhedron
Journal Volume
6
Journal Issue
12
Series
Polyhedron.
Journal Page Range
2099-2102
ISSN
0277-5387
CODEN
PLYHD

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
19026615
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
AMERICIUM 241; BENZENE; CALIFORNIUM 252; CHEMICAL REACTION KINETICS; CHLOROFORM; CURIUM 244; EUROPIUM 152; EUROPIUM 154; LUTETIUM 177; ORGANIC FLUORINE COMPOUNDS; PH VALUE; PYRAZOLES; SOLVENT EXTRACTION; TERBIUM 160; THULIUM 170
Descriptors DEC
ACTINIDE NUCLEI; ALPHA DECAY RADIOISOTOPES; AMERICIUM ISOTOPES; AROMATICS; AZOLES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BETA-PLUS DECAY RADIOISOTOPES; CALIFORNIUM ISOTOPES; CURIUM ISOTOPES; DAYS LIVING RADIOISOTOPES; ELECTRON CAPTURE RADIOISOTOPES; EUROPIUM ISOTOPES; EVEN-EVEN NUCLEI; HEAVY NUCLEI; HETEROCYCLIC COMPOUNDS; HOURS LIVING RADIOISOTOPES; HYDROCARBONS; INTERMEDIATE MASS NUCLEI; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; KINETICS; LUTETIUM ISOTOPES; MINUTES LIVING RADIOISOTOPES; NUCLEI; ODD-EVEN NUCLEI; ODD-ODD NUCLEI; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RADIOISOTOPES; RARE EARTH NUCLEI; REACTION KINETICS; SEPARATION PROCESSES; SPONTANEOUS FISSION RADIOISOTO; TERBIUM ISOTOPES; THULIUM ISOTOPES; YEARS LIVING RADIOISOTOPES