Published April 2004
| Version v1
Journal article
Synthesis, spectral characterisation and redox properties of heteroleptic ruthenium(II)-p-tolylazoimodazole-pyridine complexes
Creators
- 1. Dept. of Chemistry, The Univ. of Burdwan, Burdwan (India)
Description
Five heteroleptic ruthenium(II) complexes of formulae [Ru(RPy)2 (MeaaiMe)2](ClO4)2.H2O (1-5) (MeaaiMe = p-Me-C6H4-N=N-C3H2, RPy: R H (pyridine, 1), o-Me (o-methylpyridine, 2), p-Me (p-methylpyridine, 3), p-NMe2 (p-N,N-dimethylpyridine, 4), p-Cl (p-chloropyridine, 5) have been synthesized from ctc-[RuCl2(MeaaiMe)2] + AgNO3 and RPy. The complexes are characterized by IR, UV-Vis and 1H-NMR spectral data. They exhibit high intense MLCT transition in 520-545 nm. Cyclic voltammogram shows Ru(III)-Ru(II) couple along with ligand reductions. (author)
Additional details
Publishing Information
- Journal Title
- Indian Journal of Chemistry. Section A: Inorganic, Bio-inorganic, Physical, Theoretical and Analytical Chemistry
- Journal Volume
- 43
- Journal Issue
- 4
- Journal Page Range
- p. 786-789
- CODEN
- ICACEC
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 35077703
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL COMPOSITION; CHEMICAL PREPARATION; INFRARED SPECTRA; NMR SPECTRA; QUANTITATIVE CHEMICAL ANALYSIS; RUTHENIUM; RUTHENIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; ULTRAVIOLET SPECTRA; VOLTAMETRY
- Descriptors DEC
- CHEMICAL ANALYSIS; COMPLEXES; ELEMENTS; METALS; PLATINUM METALS; REFRACTORY METALS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS
Optional Information
- Notes
- 9 refs., 2 tabs.