Association of Plutonium isotopes with natural soil particles of different size and comparison with ¹³⁷Cs

Information on how plutonium (Pu) isotopes associate with natural soil particles of different size is very important for the interpretation involved in the application of Pu isotopes as soil erosion tracers. This work investigated the association of Pu isotopes with different particle size fractions of natural soils and compared it with that of ¹³⁷Cs. Ten bulk soils collected from two different areas were separated into different particle size fractions by a combination of wet sieving and centrifugation techniques and the sub-samples were analyzed for ¹³⁷Cs, ²³⁹Pu and ²⁴⁰Pu. Results showed that the concentrations of both ^239+240Pu and ¹³⁷Cs increase with decreased particle sizes and are closely related to the specific surface areas of soil particles, which demonstrated a similar preferential association of Pu with finer soil particles as ¹³⁷Cs. The activity ratios of ^239+240Pu/¹³⁷Cs in soil fractions increasing with increased particle size further indicated a less preferential transport of Pu with fine particles compared to ¹³⁷Cs. These results not only highlight the suitability of Pu isotopes as soil erosion tracers, but also provide useful information for assessing the migration behavior of Pu in contaminated environments. - Highlights: • Pu concentrations in the soil particles increase with decreased particle size. • Pu isotopes preferentially associate with finer soil particles like ¹³⁷Cs. • Finer soil particles bind more Pu mainly due to their larger specific surface areas. • Pu might be less preferential transported with fine soil particles compared to ¹³⁷Cs.