Published September 1, 1974 | Version v1
Journal article Metadata-only

Auger electron spectroscopic investigations of chemical shifts in some vanadium compounds

Creators

  • 1. Science Center, Rockwell International, Thousand Oaks, California 91360

Description

The Auger spectra of vanadium metal and of the compounds V2O4, V2O3, VO, VN, VC, V2S3, and VSi2 have been observed. Shifts in energy of the vanadium L3M2,3M2,3 inner-shell Auger transition peak as the result of chemical bonding effects have been measured. These shifts have been found to be related to the chemical bond ionicity as determined by the Philips-Van Vechten ionicity scale. The ratio of the anion to cation Auger peak intensities observed for the compounds can also be utilized in the determination of the surface composition.

Additional details

Identifiers

DOI
10.1063/1.1682213;

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
61
Journal Issue
5
Series
J. Chem. Phys.
Journal Page Range
2064-2070
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
6166691
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
AUGER EFFECT; CHEMICAL BONDS; CHEMICAL SHIFT; ELECTRON COLLISIONS; ENERGY-LEVEL TRANSITIONS; SURFACE PROPERTIES; VANADIUM CARBIDES; VANADIUM COMPOUNDS; VANADIUM NITRIDES; VANADIUM OXIDES; VANADIUM SILICIDES; VANADIUM SULFIDES
Descriptors DEC
CARBIDES; CARBON COMPOUNDS; CHALCOGENIDES; COLLISIONS; NITRIDES; NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SILICIDES; SILICON COMPOUNDS; SULFIDES; SULFUR COMPOUNDS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
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