Published July 2005
| Version v1
Journal article
Reactions of 1,3-dioxacycloalkanes and their 2-arsena, 2-bora, 2-germa, 2-sila, and 2-thia analogs with nitriles
Creators
- 1. Ufimskij Gosudarstvennyj Neftyanoj Tekhnicheskij Univ., Ufa (Russian Federation)
Description
New reactions of five-, six-, and seven-membered 1,3-dioxacycloalkanes and their 2-arsena, 2-bora, 2-germa, 2-sila, and 2-thia analogs with nitriles giving rise to 1,3-oxazacycloalkanes and then to amino alcohols are surveyed. The reactions under consideration, including the reactions of boronic and boric acid esters with nitriles, supplement the known chemical transformations of 1,3-dioxacycloalkanes and their 2-hetero atomic analogs and provide a wide scope for the synthesis of diverse functional derivatives on their basis
Abstract (Russian)
Представлены новые примеры реакций пяти-, шести- и семичленных 1,3-диокса-циклоалканов и их 2-арсена-, 2-бора-, 2-герма-, 2-сила- и 2-тиааналогов с нитрилами, ведущих к 1,3-оксазациклоалканам и далее к аминоспиртам. Рассмотренные в обзоре реакции, в том числе реакции циклических эфиров бороновых и борной кислот с нитрилами, дополняют известные химические превращения 1,3-диоксациклоалканов и их 2-гетероатомных аналогов и расширяют возможности синтеза разнообразных функциональных производных на их основеAdditional details
Additional titles
- Original title (Russian)
- Взаимодействие 1,3-диоксациклоалканов и их 2-арсена-, 2-бора-, 2-герма-, 2-сила- и 2-тиааналогов с нитрилами
Publishing Information
- Journal Title
- Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
- Journal Issue
- no.7
- Journal Page Range
- p. 1499-1507
- ISSN
- 1026-3500
- CODEN
- IASKEA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 37070076
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BORON COMPOUNDS; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CHEMICAL REACTIONS; ESTERS; HETEROCYCLIC COMPOUNDS; MOLECULAR STRUCTURE; NITRILES; ORGANIC BORON COMPOUNDS; REACTION INTERMEDIATES; REVIEWS
- Descriptors DEC
- DOCUMENT TYPES; KINETICS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; REACTION KINETICS; YIELDS
Optional Information
- Notes
- 56 refs., 5 tabs.