Published November 2008
| Version v1
Journal article
Electrochemical behavior of methyl hydrazine at platinum electrode
Description
Electrochemical behavior of methyl hydrazine has been studied on platinum electrode in nitric acid solution by potential cyclic sweep voltammetry. The CV results imply that the electrochemical oxidation reactions of methyl hydrazine are chemically irreversible. The kinetics parameters of electron transfer coefficient α is 0.53, diffusion coefficient D is 8.75 x 10-6 cm2/s and equilibrium potential of methyl hydrazine is 0.31 V(vs SCE). (authors)
Additional details
Publishing Information
- Journal Title
- Journal of Nuclear and Radiochemistry
- Journal Volume
- 30
- Journal Issue
- 4
- Journal Page Range
- p. 206-209
- ISSN
- 0253-9950
INIS
- Country of Publication
- China
- Country of Input or Organization
- China
- INIS RN
- 42032580
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; DIFFUSION; ELECTRIC POTENTIAL; ELECTRICAL PROPERTIES; ELECTROCHEMISTRY; ELECTRODES; ELECTRON TRANSFER; HYDRAZINE; IRREVERSIBLE PROCESSES; NITRIC ACID; OXIDATION; PLATINUM; PUREX PROCESS; VOLTAMETRY
- Descriptors DEC
- CHEMICAL REACTIONS; CHEMISTRY; ELEMENTS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; METALS; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; PLATINUM METALS; REACTION KINETICS; REPROCESSING; SEPARATION PROCESSES; TRANSITION ELEMENTS
Optional Information
- Notes
- 8 figs., 7 refs.