Published 2013
| Version v1
Book
Preparation and characterization of Gd2-xUxZr2O7+δ (0.0 ≤ x ≤ 0.25)
- 1. Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India)
- 2. Post Irradiation Examination Division, Bhabha Atomic Research Centre, Mumbai (India)
Description
A series of compositions with stoichiometry Gd2-xUxZr2O7+δ (0.0 ≤ x ≤ 0.25) were synthesized by gel-combustion method using glycine as fuel. The products have been annealed in Ar+H2 atmosphere at 1100℃ for 8h and characterized by XRD. The solubility of uranium was found to be 12.5 mol % in Gd2-xUxZr2O7+δ matrix in reducing condition and 7.5% in oxidizing condition. The analyses of the XRD data of the compositions revealed a gradual decreasing trend in unit cell parameter of cubic lattice with increasing uranium content. The high temperature behaviors of these samples were studied by high temperature XRD. (author)
Additional details
Publishing Information
- Publisher
- Bhabha Atomic Research Centre
- Imprint Place
- Mumbai (India)
- Imprint Title
- Proceedings of the nineteenth DAE-BRNS symposium and workshop on thermal analysis
- Imprint Pagination
- 749 p.
- Journal Page Range
- p. 350-354
Conference
- Title
- 19. DAE-BRNS symposium and workshop on thermal analysis
- Acronym
- THERMANS-2013
- Dates
- 19-23 Dec 2013
- Place
- Mumbai (India)
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 45027122
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- GADOLINIUM OXIDES; GLYCINE; SOL-GEL PROCESS; URANIUM OXIDES; X-RAY DIFFRACTION; ZIRCONIUM OXIDES
- Descriptors DEC
- ACTINIDE COMPOUNDS; AMINO ACIDS; CARBOXYLIC ACIDS; CHALCOGENIDES; COHERENT SCATTERING; DIFFRACTION; GADOLINIUM COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS; URANIUM COMPOUNDS; ZIRCONIUM COMPOUNDS
Optional Information
- Notes
- 8 refs., 3 figs.