Published May 1994 | Version v1
Journal article Metadata-only

Effect of medium on polymerization of 1,2-oxiranes with tetrahydrofuranate of boron trifluoride

Creators

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Khimicheskoj Fiziki

Description

The effect of a medium on the molecular mass distribution of the products of polymerization of epichlorohydrin and propylene oxide initiated by tetrahydranate of boron trifluoride was studied. It is shown that the nucleophilic solvation of the active centers with the competing components of the system makes the main contribution to the molecular mass distribution

Additional details

Additional titles

Original title (Russian)
Рол' среды в полимеризации 1,2-оксиранов под действием тетрагидрофураната трехфтористого бора

Publishing Information

Journal Title
Vysokomolekulyarnye Soedineniya, Seriya B
Journal Volume
36
Journal Issue
5
Journal Page Range
p. 856-859.
ISSN
0042-9368
CODEN
VYSBAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
26039867
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BORON COMPLEXES; CHEMICAL REACTION KINETICS; CHROMATOGRAPHY; EPOXIDES; FLUORIDES; MOLECULAR WEIGHT; ORGANIC SOLVENTS; POLYMERIZATION; SOLVATION; TETRAHYDROFURAN
Descriptors DEC
CHEMICAL REACTIONS; COMPLEXES; FLUORINE COMPOUNDS; FURANS; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; KINETICS; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; REACTION KINETICS; SEPARATION PROCESSES; SOLVENTS