Published 1979 | Version v1
Journal article Metadata-only

Influence of irradiation on oxygen-containing compounds in the presence of olefins

Creators

  • 1. Mendeleev Institute of Chemical Technology, Moscow (USSR)

Description

The relation between the structure of olefins and oxygen-containing compounds and their reactivity in radical addition, substitution and isomerization processes under γ-irradiation in a wide temperature range was examined. Correlation equations for the determination of elementary rate constants and their Arrhenius parameters are given. The compensation effect is discussed. A mechanism of product formation is proposed and the corresponding kinetic equations are derived from the steady-state principle. (author)

Additional details

Publishing Information

Journal Title
J. Radioanal. Chem.
Journal Volume
51
Journal Issue
2
Series
J. Radioanal. Chem.
Journal Page Range
337-344
ISSN
0134-0719

Conference

Title
9. Radiochemical conference.
Dates
11 - 16 Sep 1978.
Place
Piestany, Czechoslovakia.

INIS

Country of Publication
Hungary
Country of Input or Organization
Hungary
INIS RN
11499125
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Conference, Numerical Data
Descriptors DEI
ACTIVATION ENERGY; ALKENES; ARRHENIUS EQUATION; CHEMICAL REACTION KINETICS; EVALUATED DATA; GAMMA RADIATION; GRAPHS; ISOLATED VALUES; ISOMERIZATION; ORGANIC OXYGEN COMPOUNDS; RADIOLYSIS; TELOMERIZATION; THEORETICAL DATA
Descriptors DEC
CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DATA; DATA FORMS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ENERGY; HYDROCARBONS; INFORMATION; IONIZING RADIATIONS; KINETICS; NUMERICAL DATA; ORGANIC COMPOUNDS; POLYMERIZATION; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS

Optional Information

Notes
13 refs.