Published 1997 | Version v1
Book Metadata-only

X-ray photoelectron spectroscopy study of UO22+ interaction with calcite, diabase, and humic acids

Creators

  • 1. Rossijskij Nauchnyj Tsentr Kurchatovskij Inst., Moscow (Russian Federation)
  • 2. Inst. Obshchej i Neorganicheskoj Khimii RAN, Moscow (Russian Federation)
  • 3. Inst. Radiokhimii Rezenfordskogo Nauchnogo Tsentra, Drezden (Germany)

Description

Interaction of uranyl perchlorate with calcite and diabase minerals and of uranyl acetate dehydrite with humic acids was studied by the method of X-ray photoelectron spectroscopy to evaluate the degree of radionuclides mobility, uranyl compounds specifically, in the rocks adjacent to uranium deposits. It is shown that during interaction with calcite and diabase uranyl compounds are concentrated on the mineral surface and in the form of K4UO2(CO3)3 may be contained in their crystal lattice, replacing calcium ions. Humic acids interact with uranyl ions intensively than with calcium ones, the concentration of uranyl groups on the surface being higher than the one in humates volume

Abstract (Russian)

С целью оценки степени подвижности радионуклидов, в частности соединений уранила, в породах, прилегающих к урановым месторождениям, методом рентгеноэлектронной спектроскопии изучено взаимодействие перхлората уранила с минералами кальцита и диабаза, а также дигидрата ацетата уранила с гуминовыми кислотами. Показано, что при взаимодействии с кальцитом и диабазом соединения уранила сосредотачиваются на поверхности минералов и в форме K4UO2(CO3)3 могут входить в их кристаллическую решетку, замещая ионы кальция. Гуминовые кислоты взаимодействуют более с ионами кальция, при этом концентрация уранильных групп на поверхности оказывается больше, чем в объеме гуматов
Part of:
National conference on the application of X-rays, synchrotron radiation, neutrons and electrons for materials study (the continuation of All-Union Meetings on the application of X-rays for materials research). Summary of reports. Volume 2

Additional details

Additional titles

Original title (Russian)
Изучение взаимодейсвия UO

Publishing Information

Publisher
OIYaI
Imprint Place
Dubna (Russian Federation)
ISBN
5-85165-484-8
Imprint Title
National conference on the application of X-rays, synchrotron radiation, neutrons and electrons for materials study (the continuation of All-Union Meetings on the application of X-rays for materials research). Summary of reports. Volume 2
Imprint Pagination
452 p.
Journal Page Range
p. 436-441

Conference

Title
National conference on the application of X-rays, synchrotron radiation, neutrons and electrons for materials study (the continuation of All-Union Meetings on the application of X-rays for materials research)
Original Conference Title
Natsional'naya konferentsiya po primeneniyu rentgenovskogo, sinkhrotronnogo izluchenij, nejtronov i ehlektronov dlya issledovaniya materialov (prodolzhenie Vsesoyuznykh soveshchanij po primeneniyu rentgenovskikh luchej dlya issledovaniya materialov)
Dates
25-29 May 1997
Place
Dubna (Russian Federation)

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
33007733
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S54: ENVIRONMENTAL SCIENCES;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ACETATES; CALCITE; CARBONATE MINERALS; CHEMICAL REACTIONS; CHEMICAL STATE; ELECTRON SPECTRA; HUMIC ACIDS; HYDRATES; PHOTOELECTRON SPECTROSCOPY; RADIONUCLIDE MIGRATION; SPATIAL DISTRIBUTION; URANIUM DEPOSITS; URANYL PERCHLORATES
Descriptors DEC
ACTINIDE COMPOUNDS; CARBONATE MINERALS; CARBOXYLIC ACID SALTS; CHLORINE COMPOUNDS; DISTRIBUTION; ELECTRON SPECTROSCOPY; ENVIRONMENTAL TRANSPORT; GEOLOGIC DEPOSITS; HALOGEN COMPOUNDS; MASS TRANSFER; MINERAL RESOURCES; MINERALS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PERCHLORATES; RESOURCES; SPECTRA; SPECTROSCOPY; URANIUM COMPOUNDS; URANYL COMPOUNDS

Optional Information

Notes
2 refs., 1 fig. Imprint:Natsional'naya konferentsiya po primeneniyu rentgenovskogo, sinkhrotronnogo izluchenij, nejtronov i ehlektronov dlya issledovaniya materialov (prodolzhenie Vsesoyuznykh soveshchanij po primeneniyu rentgenovskikh luchej dlya issledovaniya materialov). Sbornik dokladov. Tom 2
Secondary number(s)
JINR-R--14-97-343