Published December 1, 2019 | Version v1
Journal article

Removal of radionuclides and toxic metal ions from water with use of new highly effective sorbiting material

  • 1. Department of Automated Design and Modeling Systems, Astrakhan State University of Architecture and Civil Engineering, 18, Tatishchev St., Astrakhan 414056 (Russian Federation)
  • 2. Department of Analytic and Physical Chemistry, Astrakhan State University, 20a, Tatishchev St., Astrakhan 414056 (Russian Federation)

Description

The adsorption of radionuclides of strontium, rubidium, cesium, uranium and some toxic metal ions from water streams using flasks has been experimentally and theoretically studied. When studying the adsorption of a number of metal ions on them, it was found that in a wide range of pH many cations are durably adsorbed, and in some cases irreversible sorption is observed. Ammonium, potassium, rubidium, cesium, iron, cobalt, nickel, manganese (II), chromium (III), zinc, cadmium, lead, mercury, copper and rare earth ions are durably adsorbed. At the same time, sodium, aluminum, gallium, zirconium, and molybdenum (VI) ions are captured during adsorption from solutions. These ions can be desorbed not only by acidification of the eluting solution, but also by washing the sorbent with water. An analysis of the results obtained in the study of the adsorption of cations made it possible to draw an initial conclusion: those ions that contain vacant d or f orbitals form strong adsorption complexes with flasks. Flasks are used to extract potassium, rubidium, cesium, calcium, strontium and barium ions from water of varying degrees of salinity. (paper)

Availability note (English)

Available from http://dx.doi.org/10.1088/1757-899X/687/6/066057

Additional details

Publishing Information

Journal Title
IOP Conference Series. Materials Science and Engineering (Online)
Journal Volume
687
Journal Issue
6
Journal Page Range
[6 p.]
ISSN
1757-899X

Conference

Title
International Conference on Construction, Architecture and Technosphere Safety
Dates
10 Apr 2018
Place
Chelyabinsk (Russian Federation)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
53007006
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ACIDIFICATION; ADSORPTION; CATIONS; CESIUM; PH VALUE; POTASSIUM; RADIOISOTOPES; RARE EARTHS; RUBIDIUM; SALINITY; STRONTIUM
Descriptors DEC
ALKALI METALS; ALKALINE EARTH METALS; CHARGED PARTICLES; ELEMENTS; IONS; ISOTOPES; METALS; SORPTION