Published January 1986 | Version v1
Report Metadata-only

Iodine hydrolysis reactions; preliminary species identification and rate measurements

Creators

  • 1. UKAEA Atomic Energy Research Establishment, Harwell. Chemistry Div.

Description

Curve-fitting techniques have been used with time-resolved spectra of aqueous iodine solutions to measure the parameters of absorption bonds in the electronic spectra of the solutions. Data were combined with a FACSIMILE computer model of the hydrolysis reactions to provide rate constants for the individual reactions. Measurements have been completed for a 2x10-6 M solution of iodine in pure water, and for similar solutions containing silver ions; a set of rate constants was derived which fits all these solutions. (U.K.)

Additional details

Publishing Information

ISBN
0-7058-1073-9
Imprint Title
Specialists' workshop on iodine chemistry in reactor safety
Imprint Pagination
365 p.
Journal Page Range
p. 47-61.
Report number
AERE-R--11974

Conference

Title
Specialists' workshop on iodine chemistry in reactor safety.
Dates
11-12 Sep 1985.
Place
Harwell (UK).

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
17064441
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference, Numerical Data, Non-conventional Literature
Descriptors DEI
ABSORPTION SPECTRA; AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; COMPUTER CODES; EXPERIMENTAL DATA; HYDROLYSIS; IODINE; MATHEMATICAL MODELS; OXIDATION; PH VALUE; REACTOR ACCIDENTS; REDUCTION; SPECTROPHOTOMETRY
Descriptors DEC
ACCIDENTS; CHEMICAL REACTIONS; DATA; DECOMPOSITION; DISPERSIONS; ELEMENTS; HALOGENS; HOMOGENEOUS MIXTURES; INFORMATION; KINETICS; MIXTURES; NONMETALS; NUMERICAL DATA; REACTION KINETICS; SOLUTIONS; SOLVOLYSIS; SPECTRA