Published 1987
| Version v1
Book
Study of oxalate compounds of nickel
Creators
Description
The Ni(NO3)2-M2C2O4-H2O(M=L+-Cs+, NH4+) in aqueous solutions at 25 deg C and molar relation C2O42-:Ni2+=0.5-8.0 are studied by the method of residual concentrations. It is established that the NiC2O4x2H2O(1) compound is formed in all systems in a solid phase, and Cs(Ni(C2O4)2)x4H2O(2) - in the system with cesium oxalate. Complex 2, unlike compound 1, dissolves well in water and does not dissolve in the cesium oxalate excess. At 150 deg C complex 2 losses crystallization water and in 310-500 deg C interval it decomposes with Cs2NiO2 formation
Additional details
Additional titles
- Original title (Russian)
- Исследование оксалатных соединений никеля
- Augmented title (English)
- Nickel oxalate complexes with alkali metal compounds
Publishing Information
- Publisher
- Metsniereba.
- Imprint Place
- Tbilisi (USSR)
- Imprint Title
- Investigations in chemistry of complexes and compounds of certain transition and rare metals. No. 4
- Journal Page Range
- p. 172-176.
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 20028788
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CESIUM COMPOUNDS; CHEMICAL PREPARATION; HYDRATES; NICKEL COMPLEXES; OXALATES; PYROLYSIS; QUANTITY RATIO; SOLUBILITY
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CARBOXYLIC ACID SALTS; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; DISPERSIONS; HOMOGENEOUS MIXTURES; MIXTURES; SOLUTIONS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- 2 refs.; 2 tabs. Imprint:Issledovaniya v oblasti khimii kompleksnykh i prostykh soedinenij nekotorykh perekhodnykh i redkikh metallov. Vypusk 4.