Published December 1980
| Version v1
Journal article
Hydroxide complexes of lanthanides
Creators
- 1. Amsterdam Univ. (Netherlands). Natuurkundig Lab.
- 2. Amsterdam Univ. (Netherlands). Lab. voor Analytische Chemie
Description
From the precipitation borderline in the pM'-pH diagram, determined experimentally under CO2-free conditions, the stability constants of the mononuclear and polynuclear species of gadolinium hydroxide have been established. The values found are log*β1 = - 7.3, log*β2 = - 14.6, log*β3 = - 21.9, log*βsub(4.3) = - 19.0 and log*Ksub(s0) = 17.0. They refer to fresh precipitates, prepared at room temperature in sodium perchlorate medium with an ionic strength of 1. (author)
Additional details
Additional titles
- Subtitle (English)
- 3. Gadolinium(III) in perchlorate medium
Publishing Information
- Journal Title
- Talanta
- Journal Volume
- 27
- Journal Issue
- 12
- Series
- Talanta.
- Journal Page Range
- 1047-1050
- ISSN
- 0039-9140
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- United Kingdom
- INIS RN
- 12584078
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; GADOLINIUM COMPLEXES; GADOLINIUM HYDROXIDES; HYDROLYSIS; PH VALUE; PRECIPITATION; SODIUM PERCHLORATES; STABILITY
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; DECOMPOSITION; DISPERSIONS; GADOLINIUM COMPOUNDS; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; HYDROXIDES; KINETICS; MIXTURES; OXYGEN COMPOUNDS; PERCHLORATES; RARE EARTH COMPLEXES; RARE EARTH COMPOUNDS; REACTION KINETICS; SEPARATION PROCESSES; SODIUM COMPOUNDS; SOLUTIONS; SOLVOLYSIS