Published September 2018
| Version v1
Journal article
Kinetic Features of the Formation of Zinc Complex with Hexa(m-Trifluoromethylphenyl)benzoporphyrazine in a Nitrogen-Containing Base–Benzene System
Description
The effect n-butylamine, tert-butylamine, piperidine, and morpholine additives have on the kinetics of complex formation between zinc acetate and hexa(m-trifluoromethylphenyl)benzoporphyrazine in benzene is studied. A possible scheme for their complexation is proposed. It is established that the rate and activation parameters of the process are affected by the proton-acceptor capacity of the base and its spatial structure.
Additional details
Identifiers
Publishing Information
- Journal Title
- Russian Journal of Physical Chemistry
- Journal Volume
- 92
- Journal Issue
- 9
- Journal Page Range
- p. 1664-1669
- ISSN
- 0036-0244
- CODEN
- RJPCAR
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51023414
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETATES; ADDITIVES; BENZENE; MORPHOLINES; NITROGEN; PIPERIDINES; PROTONS; REACTION KINETICS; ZINC COMPLEXES
- Descriptors DEC
- AMINES; AROMATICS; AZINES; BARYONS; CARBOXYLIC ACID SALTS; COMPLEXES; ELEMENTARY PARTICLES; ELEMENTS; ETHERS; FERMIONS; HADRONS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; KINETICS; NONMETALS; NUCLEONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PYRIDINES
Optional Information
- Copyright
- Copyright (c) 2018 Pleiades Publishing, Ltd.