Published September 20, 1985
| Version v1
Journal article
A pulse radiolysis study of the reactivity of Cl2- and Br2- relative to vanadyl ions in aqueous solution
Description
The authors measure rate constants of the reactions of vanadium(IV) ions with C12- and Br2- ions by pulse radiolysis in acidic aqueous solution. These rate constants increase with increasing acidity. This effect is attributed to ''equalization'' of the vanadium(IV) and vanadium(V) ion species in strongly acidic media
Additional details
Publishing Information
- Journal Title
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.)
- Journal Volume
- 34
- Journal Issue
- 3,PT.2
- Series
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.).
- Journal Page Range
- 630-631
- ISSN
- 0568-5230
- CODEN
- BACCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 18030863
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ACTIVATION ENERGY; AQUEOUS SOLUTIONS; BROMINE COMPOUNDS; CHEMICAL REACTION KINETICS; CHLORINE COMPOUNDS; ELECTRON BEAMS; ELECTRON-ION COLLISIONS; HYDROCHLORIC ACID; OXIDATION; PH VALUE; PULSED IRRADIATION; RADIOLYSIS; REDOX POTENTIAL; SPECTROPHOTOMETRY; VANADIUM COMPOUNDS
- Descriptors DEC
- BEAMS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; COLLISIONS; DECOMPOSITION; DISPERSIONS; ELECTRON COLLISIONS; ENERGY; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; ION COLLISIONS; IRRADIATION; KINETICS; LEPTON BEAMS; MIXTURES; PARTICLE BEAMS; RADIATION EFFECTS; REACTION KINETICS; SOLUTIONS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- Cover-to-cover translation of Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (USSR).