Published December 3, 2007 | Version v1
Journal article

Enhanced photoelectrochemical responses of ZnO films through Ga and N codoping

  • 1. National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

Description

We report on the crystallinity and photoelectrochemical (PEC) response of ZnO thin films codoped by Ga and N. The ZnO:(Ga,N) thin films were deposited by cosputtering at room temperature and followed by postannealing at 500 deg. C in air for 2 h. We found that ZnO:(Ga,N) thin films exhibited significantly enhanced crystallinity compared to ZnO doped solely with N at the same growth conditions. Furthermore, ZnO:(Ga,N) thin films exhibited enhanced N incorporation over ZnO doped solely with N at high temperatures. As a result, ZnO:(Ga,N) thin films achieved dramatically improved PEC response, compared to ZnO thin films doped solely with N at any conditions. Our results suggest a general way to improve PEC response for wide-band-gap oxides

Additional details

Identifiers

Publishing Information

Journal Title
Applied Physics Letters
Journal Volume
91
Journal Issue
23
Journal Page Range
p. 231909-231909.3
ISSN
0003-6951
CODEN
APPLAB

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
39038412
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
AIR; ANNEALING; CRYSTAL GROWTH; DEPOSITION; DOPED MATERIALS; GALLIUM; NITROGEN; SEMICONDUCTOR MATERIALS; TEMPERATURE RANGE 0273-0400 K; TEMPERATURE RANGE 0400-1000 K; THIN FILMS; ZINC OXIDES
Descriptors DEC
CHALCOGENIDES; ELEMENTS; FILMS; FLUIDS; GASES; HEAT TREATMENTS; MATERIALS; METALS; NONMETALS; OXIDES; OXYGEN COMPOUNDS; TEMPERATURE RANGE; ZINC COMPOUNDS

Optional Information

Notes
(c) 2007 American Institute of Physics