Published November 1999
| Version v1
Journal article
Moessbauer studies of heteroleptic Sn(II) derivatives
Creators
- 1. Universidade Federal de Minas Gerais, Departamento de Quimica (Brazil)
- 2. Universite Catholique de Louvain, Laboratoire de Chemie Inorganique et Nucleaire INAN, NUCL (Belgium)
Description
The heteroleptic Sn(II) derivatives, [Sn(η5-C5Me5)Cl] (1), [{Sn(η5-C5Me4SiMe2But)} {Sn(η5-C5Me4SiMe2But)(OSO2CF3)}] (2), [{Sn(η5-C5Me5)}{Sn(η5-C5Me5)(OSO2CF3)}] (3) and [(Sn{N(SiMe3)2}{OSO2CF3})2] (4), were prepared and characterized by 119Sn Moessbauer spectroscopy, as well as by other techniques such as multinuclear NMR (solution- and solid-state) spectroscopy and X-ray crystallography. The 119Sn Moessbauer spectroscopic data were in good agreement with the other solid state results rendering additional support for the elucidation of bonding and structural features of these compounds
Additional details
Identifiers
Publishing Information
- Journal Title
- Hyperfine Interactions
- Journal Volume
- 122
- Journal Issue
- 3-4
- Journal Page Range
- p. 327-331
- ISSN
- 0304-3843
- CODEN
- HYINDN
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40068519
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- BONDING; CRYSTALLOGRAPHY; MOESSBAUER EFFECT; NUCLEAR MAGNETIC RESONANCE; SOLIDS; SOLUTIONS; SPECTROSCOPY; TIN 119; X RADIATION
- Descriptors DEC
- DAYS LIVING RADIOISOTOPES; DISPERSIONS; ELECTROMAGNETIC RADIATION; EVEN-ODD NUCLEI; FABRICATION; HOMOGENEOUS MIXTURES; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; IONIZING RADIATIONS; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; JOINING; MAGNETIC RESONANCE; MIXTURES; NUCLEI; RADIATIONS; RADIOISOTOPES; RESONANCE; STABLE ISOTOPES; TIN ISOTOPES
Optional Information
- Copyright
- Copyright (c) 1999 Kluwer Academic Publishers