Published December 18, 1985
| Version v1
Journal article
Properties of Sc7Cl10 revisited
- 1. AT and T Bell Labs., Murray Hill, NJ
Description
The properties of the pseudo-one-dimensional compound Sc7Cl10 have been reinvestigated down to 4.2 K. Sc7Cl10 is a good conductor and has local magnetic moments (0.90 μB/formula unit). The EPR spectrum shows a line without hyperfine structure with a g value of 1.985. The lack of hyperfine structure suggests rapid spin diffusion, possibly as a result of the metallic conduction inferred from resistance and photoemission data. The observed g value and the moment determined from magnetic susceptibility indicate about one localized magnetic moment per 2 formula units, an assignment that is inconsistent with the room-temperature structure of Sc7Cl10 and simple magnetic models. 11 references, 2 figures
Additional details
Publishing Information
- Journal Title
- Inorg. Chem.
- Journal Volume
- 24
- Journal Issue
- 26
- Series
- Inorg. Chem.
- Journal Page Range
- 4624
- ISSN
- 0020-1669
- CODEN
- INOCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 17067840
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CHEMICAL PREPARATION; ELECTRIC CONDUCTIVITY; ELECTRON SPIN RESONANCE; EXPERIMENTAL DATA; FARADAY METHOD; MAGNETIC MOMENTS; MAGNETIC SUSCEPTIBILITY; SCANDIUM CHLORIDES; ULTRALOW TEMPERATURE
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; DATA; ELECTRICAL PROPERTIES; HALIDES; HALOGEN COMPOUNDS; INFORMATION; MAGNETIC PROPERTIES; MAGNETIC RESONANCE; NUMERICAL DATA; PHYSICAL PROPERTIES; RESONANCE; SCANDIUM COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS