Published 1990 | Version v1
Journal article Metadata-only

Crystal and molecular structure of bis-(pentamethylcyclopentadienyltricarbonyl) tungsten (1) [Me5C5W(CO)3]2

Creators

  • 1. AN Azerbajdzhanskoj SSR, Baku (USSR). Inst. Teoreticheskikh Problem Khimicheskoj Tekhnologii
  • 2. AN Azerbajdzhanskoj SSR, Baku (USSR). Inst. Fizicheskoj i Neorganicheskoj Khimii

Description

By the method of X-ray diffraction analysis monocrystals of [Me5C5W(CO)3]2 binuclear complex are studied. The crystals are monoclinic: a=17.125(2), b=0.0925(9), c=9.3755(7) A, β=115.687(6) deg, Z=2, sp. gr. C2. Molecule of the given complex in contrast to molecules of previously studied complexes of [CpM(CO)3]2, where M=Cr,Mo,W, with trans-conformation in crystal state has cis-conformation with intrinsic symmetry C2

Additional details

Additional titles

Original title (Russian)
Кристаллическая и молекулярная структура бис-(пентаметилциклопентадиенилтрикарбонил) вольфрама (1) [Ме

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
16
Journal Issue
10
Series
Koord. Khim.
Journal Page Range
1343-1347
ISSN
0132-344X
CODEN
KOKHD

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
22041630
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; CARBONYLS; DIENES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; MONOCRYSTALS; SPACE GROUPS; TUNGSTEN COMPLEXES
Descriptors DEC
COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; HYDROCARBONS; ORGANIC COMPOUNDS; POLYENES; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES