Comparison of nonperturbative variational approximations to the scattering amplitude for a Yukawa potential
Creators
- 1. Department of Chemistry, Drexel University, Philadelphia, Pennsylvania 19104
Description
Variational methods for calculating approximations to the scattering amplitude of a spinless particle from a Yukawa potential are compared. These arise from the variation of functionals that depend on trial forms of the Heitler operator K or the transition operator T. The trial forms are nonperturbative, and the variational principle is applied in the free particle and partial wave basis to obtain independent approximations. In addition, no artificial separability constraint is imposed on the momentum space representation of either the trial T or K. The full free particle Green's function is utilized without basis set truncation in all of the calculations. The different approximations provide a choice of technique in the event that one or the other variational method is unstable. The results at two representative energies are in good agreement with an exact calculation
Additional details
Identifiers
- DOI
- 10.1063/1.434761;
Publishing Information
- Journal Title
- The Journal of Chemical Physics
- Journal Volume
- 67
- Journal Issue
- 12
- Series
- J. Chem. Phys.
- Journal Page Range
- 5415-5418
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 9368694
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- GREEN FUNCTION; PARTIAL WAVES; SCATTERING; SCATTERING AMPLITUDES; VARIATIONAL METHODS; YUKAWA POTENTIAL
- Descriptors DEC
- AMPLITUDES; FUNCTIONS; NUCLEAR POTENTIAL
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent