Published December 15, 1977 | Version v1
Journal article

Comparison of nonperturbative variational approximations to the scattering amplitude for a Yukawa potential

  • 1. Department of Chemistry, Drexel University, Philadelphia, Pennsylvania 19104

Description

Variational methods for calculating approximations to the scattering amplitude of a spinless particle from a Yukawa potential are compared. These arise from the variation of functionals that depend on trial forms of the Heitler operator K or the transition operator T. The trial forms are nonperturbative, and the variational principle is applied in the free particle and partial wave basis to obtain independent approximations. In addition, no artificial separability constraint is imposed on the momentum space representation of either the trial T or K. The full free particle Green's function is utilized without basis set truncation in all of the calculations. The different approximations provide a choice of technique in the event that one or the other variational method is unstable. The results at two representative energies are in good agreement with an exact calculation

Additional details

Identifiers

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
67
Journal Issue
12
Series
J. Chem. Phys.
Journal Page Range
5415-5418
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
9368694
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
GREEN FUNCTION; PARTIAL WAVES; SCATTERING; SCATTERING AMPLITUDES; VARIATIONAL METHODS; YUKAWA POTENTIAL
Descriptors DEC
AMPLITUDES; FUNCTIONS; NUCLEAR POTENTIAL

Optional Information

Notes
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