Published 1979 | Version v1
Journal article Metadata-only

Oxidation of the cyclohexadienyl radical by metal ions

Creators

  • 1. Mount Vernon Hospital, Northwood (UK). Gray Lab.

Description

The rates of oxidation of the cyclohexadienyl radical by metal ions in water have been measured. The bimolecular rate constants and corresponding reduction potentials are presented for: Fe(C2O4)33-; Cu(H2O)62+; Fe(H2O)63+; and Ce4+.nH2O. Oxidation of the cyclohexadienyl radical by V(H2O)63+ and Cr(H2O)63+ ions was not observed. It is suggested that the reduction potential of the cyclohexadienyl radical lies between -0.25 V and 0 V. (author)

Additional details

Additional titles

Subtitle (English)
A pulse radiolysis study

Publishing Information

Journal Title
Radiat. Phys. Chem.
Journal Volume
13
Journal Issue
5-6
Series
Radiat. Phys. Chem.
Journal Page Range
155-157
ISSN
0146-5724

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
10493786
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ABSORPTION SPECTRA; AQUEOUS SOLUTIONS; BENZENE; CERIUM COMPOUNDS; CHEMICAL REACTION KINETICS; CHROMIUM COMPOUNDS; COPPER COMPOUNDS; CYCLOALKENES; DIENES; EXPERIMENTAL DATA; GRAPHS; IONS; IRON COMPOUNDS; ISOLATED VALUES; OXIDATION; PULSES; RADICALS; RADIOLYSIS; VANADIUM COMPOUNDS; WATER
Descriptors DEC
ALKENES; AROMATICS; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DATA; DATA FORMS; DECOMPOSITION; DISPERSIONS; HOMOGENEOUS MIXTURES; HYDROCARBONS; HYDROGEN COMPOUNDS; INFORMATION; KINETICS; MIXTURES; NUMERICAL DATA; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; POLYENES; RADIATION EFFECTS; RARE EARTH COMPOUNDS; REACTION KINETICS; SOLUTIONS; SPECTRA; TRANSITION ELEMENT COMPOUNDS