Published September 2008 | Version v1
Journal article

Low-temperature radiation-induced cracking of liquid hydrocarbons

  • 1. PetroBeam Inc., 151 Heartland Blvd, Edgewood, NY 11717-8374 (United States)

Description

Conditions of chain cracking reactions in liquid hydrocarbons at lowered temperatures are discussed subject to contribution of the long-living radiation-excited molecular states. It is predicted that chain reactions of hydrocarbon degradation can proceed without thermal activation at the high dose rates of ionizing irradiation. In this process, both initiation and propagation of the chain are caused only by the action of radiation. Experimental verification has allowed observation of low-temperature chain cracking reactions in high-viscous oil

Availability note (English)

Available from http://dx.doi.org/10.1016/j.radphyschem.2008.07.001

Additional details

Identifiers

DOI
10.1016/j.radphyschem.2008.07.001;
PII
S0969-806X(08)00162-X;

Publishing Information

Journal Title
Radiation Physics and Chemistry (1993)
Journal Volume
77
Journal Issue
9
Journal Page Range
p. 1069-1073
ISSN
0969-806X
CODEN
RPCHDM

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
40001615
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CHAIN REACTIONS; CHEMICAL RADIATION EFFECTS; CRACKING; DOSE RATES; HYDROCARBONS; IRRADIATION; LIQUIDS
Descriptors DEC
CHEMICAL REACTIONS; DECOMPOSITION; FLUIDS; ORGANIC COMPOUNDS; PYROLYSIS; RADIATION EFFECTS; THERMOCHEMICAL PROCESSES

Optional Information

Copyright
Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.