Published January 1, 2009 | Version v1
Journal article Metadata-only

Cation-cation interactions, magnetic communication and reactivity of the pentavalent uranium ion (U(NR)2)+

Creators

  • 1. Los Alamos National Laboratory, NM (United States)

Description

The dimeric bis(imido) uranium complex ({U(NtBu)2(I)(tBu2bpy)}2) (see picture; U green, N blue, I red) has cation-cation interactions between (U(NR)2)+ ions. This f1-f1 system also displays f orbital communication between uranium(V) centers at low temperatures, and can be oxidized to generate uranium(VI) bis(imido) complexes.

Availability note (English)

Available from http://permalink.lanl.gov/object/tr?what=info:lanl-repo/lareport/LA-UR-09-00903

Additional details

Identifiers

URL
http://permalink.lanl.gov/object/tr?what=info:lanl-repo/lareport/LA-UR-09-00903;
DOI
10.1002/anie.200806190;

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Issue
Issue Jan 2009
Journal Page Range
vp.
ISSN
1433-7851

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
41094409
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CATIONS; ELECTRONIC STRUCTURE; URANIUM COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; CHARGED PARTICLES; COMPLEXES; IONS

Optional Information

Contract/Grant/Project number
AC52-06NA25396
Notes
doi 10.1002/anie.200806190
Funding organization
US Department of Energy (United States)
Secondary number(s)
LA-UR--09-00903