Published December 24, 2012 | Version v1
Journal article

Measurement of the valence band-offset in a PbSe/ZnO heterojunction by x-ray photoelectron spectroscopy

  • 1. School of Electrical and Computer Engineering, University of Oklahoma, Norman, Oklahoma 73019 (United States)
  • 2. State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050 (China)
  • 3. Deparment of Physics, University of Oklahoma, Norman, Oklahoma 73019 (United States)

Description

A heterojunction of PbSe/ZnO has been grown by molecular beam epitaxy. X-ray photoelectron spectroscopy was used to directly measure the valence-band offset (VBO) of the heterojunction. The VBO, ΔEV, was determined as 2.51 ± 0.05 eV using the Pb 4p3/2 and Zn 2p3/2 core levels as a reference. The conduction-band offset, ΔEC, was, therefore, determined to be 0.59 ± 0.05 eV based on the above ΔEV value. This analysis indicates that the PbSe/ZnO heterojunction forms a type I (Straddling Gap) heterostructure.

Additional details

Identifiers

Publishing Information

Journal Title
Applied Physics Letters
Journal Volume
101
Journal Issue
26
Journal Page Range
p. 261601-261601.4
ISSN
0003-6951
CODEN
APPLAB

Optional Information

Notes
(c) 2012 American Institute of Physics