Structures of some complexes containing the ReIVCl4 unit
- 1. Western Australia Univ., Nedlands, WA (Australia). Dept. of Chemistry
- 2. Australian National Univ., Canberra, ACT (Australia). Research School of Chemistry
Description
The X-ray crystal structure determinations of five complexes of rhenium(IV) containing the ReCl4L2 unit, with L monodentate, are reported, one at 92 K. Small single crystals of the compounds were mounted on the Siemens P3/P4 x-ray diffractometer, and reflection intensity data were collected. The data were processed by using the program suite PROFIT. The Re-Cl bond lengths in several ReIVCl4L2 octahedral complexes are compared, and no distinct trans-effect of the donor atom on the chlorine atoms is seen either where L is monodentate or where L2 is a chelate ligand. It is concluded that the effect of chelation in the ligand much overrides the electronic effects of its component donor atom on the chloride attached to rhenium. 10 refs., 12 tabs., 5 figs
Additional details
Publishing Information
- Journal Title
- Australian Journal of Chemistry
- Journal Volume
- 49
- Journal Issue
- 4
- Journal Page Range
- p. 489-496.
- ISSN
- 0004-9425
- CODEN
- AJCHAS
INIS
- Country of Publication
- Australia
- Country of Input or Organization
- Australia
- INIS RN
- 28012475
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; CHLORINE COMPOUNDS; EXPERIMENTAL DATA; LIGANDS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; P CODES; RHENIUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; COMPLEXES; COMPUTER CODES; DATA; DIFFRACTION; HALOGEN COMPOUNDS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPLEXES