Published 1984
| Version v1
Journal article
Crystal structure of [(C2H5)4N]4[(VO)2(OH2)4UMo12O42]x8H2O
- 1. Moskovskij Gosudarstvennyj Univ. (USSR)
Description
The X-ray diffraction study was made of a new heteropolycomplex being a part of the [(C2H5)4N]4[(VO)2(OH2)4UMo12O42]x8H2O crystals (REhD-4 diffractometer, MoKsub(α)-radiation, 4693 reflections, R=0.041) The crystals were found to have a monoclinic lattice with a=13.433(2), b=22.919(5), c=12.889(3) A, γ=90.69(1) deg, z=2 space group P21/n. Structural crystal units are [(VO2(OH)2)4UMo12O42]14- complex anions, tetraethylammonium cations and water molecules. The [(VO)2(OH2)4UMo12O42]4- complex anion is constructed of the [UMo12O42]8- anion, which coordinates two VO2+ ions presenting for this purpose three coordination points for each of them. Two water molecules supplement the coordination vanadium polyhedron up to the octahedron
Additional details
Additional titles
- Original title (Russian)
- Кристаллическая структура [(C
Publishing Information
- Journal Title
- Koord. Khim.
- Journal Volume
- 10
- Journal Issue
- 7
- Series
- Koord. Khim.
- Journal Page Range
- 993-997
- ISSN
- 0132-344X
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 16044617
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- BOND ANGLE; HETEROPOLYANIONS; HYDRATES; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MOLYBDENUM COMPLEXES; MONOCLINIC LATTICES; MONOCRYSTALS; OXYGEN COMPOUNDS; QUATERNARY COMPOUNDS; SPACE GROUPS; URANIUM COMPLEXES; VANADIUM COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; AMINES; ANIONS; CHARGED PARTICLES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DISTANCE; IONS; ORGANIC COMPOUNDS; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES