Deltafunction model for the helium dimer
Description
The helium dimer 4He2 has recently been detected, confirming earlier ab initio predictions of stability for a single bound state with binding energy of 1.310 mK. The predicted potential minimum is at 2.96 Angstrom, with a radial distribution function peaking at 6.96 Angstrom. We model this system using a Dirac bubble potential, which also admits just one bound J = 0 state. With the bubble located at 6.96 Angstrom, an overlap of 0.9994 with the ab initio wave function is obtained. An average internuclear distance of 52.6 Angstrom is calculated, in good agreement with the ab initio result. The root mean square deviation from the mean, 48.0 angstrom, indicates an enormous spread of the radial wave function. Also consistent with our model is the absence of bound states for the isotopic variants 3He4He and 3He2. Cross sections for helium-helium scattering are also computed, using both a partial-wave expansion and the Born approximation. General trends in the energy dependence of the total cross section are accounted for, in qualitative agreement with experimental results. 13 refs., 4 figs
Additional details
Publishing Information
- Journal Title
- International Journal of Quantum Chemistry
- Journal Volume
- 53
- Journal Issue
- 4
- Journal Page Range
- p. 413-418.
- ISSN
- 0020-7608
- CODEN
- IJQCB2
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 28060437
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- ATOM-ATOM COLLISIONS; CROSS SECTIONS; DELTA FUNCTION; DIMERS; DISTRIBUTION FUNCTIONS; ENERGY DEPENDENCE; HELIUM 4; INTERATOMIC DISTANCES; SCATTERING AMPLITUDES; WAVE FUNCTIONS
- Descriptors DEC
- AMPLITUDES; ATOM COLLISIONS; COLLISIONS; DISTANCE; EVEN-EVEN NUCLEI; FUNCTIONS; HELIUM ISOTOPES; ISOTOPES; LIGHT NUCLEI; NUCLEI; STABLE ISOTOPES