Published 1983 | Version v1
Journal article Metadata-only

Coordination compounds of titanium (4), zirconium (4) and hafnium (4) with thourea

Creators

  • 1. Kishinevskij Gosudarstvennyj Univ. (USSR)
  • 2. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii
  • 3. Kishinevskij Politekhnicheskij Inst. (USSR)

Description

Adducts of titanium, zirconium and hafnium tetrachlorides are synthesized with thiourea of the MCl4xthio and MCl4x2thio composition. On the basis of studying IR spectra of the compounds obtained it is shown that the thiourea is coordinated to titanium, zirconium and hafnium through the sulfur atom. An assumption is made that in complexes of the MCl4x2thio composition only one ligand molecule is coordinated to metal, while the second one is retained in the complex by hydrogen bonds

Additional details

Additional titles

Original title (Russian)
Координационные соединения титана (4), циркония (4) и гафния (4) с тиомочевиной

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
28
Journal Issue
4
Series
Zh. Neorg. Khim.
Journal Page Range
910-914
ISSN
0044-457X

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
15030227
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ADDUCTS; CHEMICAL PREPARATION; CHLORIDES; HAFNIUM COMPLEXES; INFRARED SPECTRA; THIOUREAS; ZIRCONIUM COMPLEXES
Descriptors DEC
CARBONIC ACID DERIVATIVES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).