Published September 2019 | Version v1
Journal article

Fisher information of radial wavefunctions for relativistic hydrogenic atoms

  • 1. Faculty of Science, Kanagawa University, 2946, 6-233 Tsuchiya, Hiratsuka, Kanagawa, 259-1293 (Japan)

Description

Highlights: • We present Fisher information per binding energy for relativistic hydrogenic atoms. • The relativistic effect makes the information increase for heavy atoms. • The inverse participation ratio decreases monotonically with Z to the contrary. -- Abstract: We calculate Fisher information and the inverse participation ratio normalised by the electric binding energy for the relativistic hydrogenic atoms based on the radial wavefunctions in position space. Fisher information rapidly decreases as the atomic number increases, but it increases again for heavy atoms for S1/2 and P1/2 states due to the relativistic effect. We consider not only the ground state but also excited states by numerically evaluating the generalised Laguerre polynomials in the exact Dirac's relativistic radial wavefunctions. This study contrasts with the previous studies of the relativistic many-electron systems (i.e., ground-state neutral atoms), where numerical densities were employed.

Additional details

Identifiers

DOI
10.1016/j.cplett.2019.136618;
PII
S0009261419305901;

Publishing Information

Journal Title
Chemical Physics Letters
Journal Volume
731
Journal Page Range
vp.
ISSN
0009-2614
CODEN
CHPLBC

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
55101344
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ATOMIC NUMBER; ELECTRON DENSITY; EXCITED STATES; GROUND STATES; LAGUERRE POLYNOMIALS; RELATIVISTIC RANGE; WAVE FUNCTIONS
Descriptors DEC
ENERGY LEVELS; ENERGY RANGE; FUNCTIONS; POLYNOMIALS

Optional Information

Copyright
Copyright (c) 2019 Elsevier B.V. All rights reserved.