Published July 1988 | Version v1
Journal article

Preparation and investigation of tetramethylammonium hydroiodate crystals

  • 1. Erevanskij Gosudarstvennyj Univ. (USSR)

Description

It is shown that acid salt of N(CH3)4IO3XHIO3XH2O composition forms in N(CH3)4IO3-HIO3-H2O system. Composition and peculiarities of the structure were investigated by the methods of infrared spectroscopy, thermal analysis and nuclear quadrupole resonance. The obtained data testify to the presence of two nonequivalent iodine atoms in crystal unit cell; one of them enters IO3- group, another - HIO3 group. IO3- and HIO3 groups are bound by hydrogen bonds. Hydroiodate crystallohydrate transforms into tetramethylammonium pyroiodate at temperatures above 140 deg C

Additional details

Additional titles

Original title (Russian)
Получение и исследование кристаллов гидройодата тетраметиламмония

Publishing Information

Journal Title
Kristallografiya
Journal Volume
33
Journal Issue
4
Series
Kristallografiya.
Journal Page Range
920-924
ISSN
0023-4761
CODEN
KRISA

Conference

Title
6. All-union conference on crystal growth.
Dates
1985.
Place
Tsakhkadzor (USSR).