Published 1993 | Version v1
Journal article Metadata-only

m-tolueneboronic acid adduct of technetium tris(dimethylglyoxime). Synthesis, structural analysis, and characterization

Creators

  • 1. Dept. of Technical Physics, Peking Univ., Beijing, BJ (China)
  • 2. Dept. of Chemistry, Peking Univ., Beijing, BJ (China)

Description

TcCl(dmg)3BC6H4CH3 has been prepared by template synthesis. Its 1H NMR, IR and UV/Vis spectra were measured and its crystal and molecular structures were determined by X-ray diffraction. The recorded data were refined by least squares to R = 0.044. The crystal parameters are as follows: triclinic, space group. P anti 1, a = 8.581(1), b = 11.996(3), c = 13.364(4) A, α = 96.71(2) , β = 92.14(2) , γ = 108.24(2) , and Z = 2. The molecule has a capped trigonal prismatic geometry. The coordination distances are 2.046-2.132 (average 2.084) for Tc-N and 2.410 for Tc-Cl. (orig.)

Additional details

Publishing Information

Journal Title
Radiochimica Acta
Journal Volume
63
Journal Page Range
p. 213-215.
ISSN
0033-8230
CODEN
RAACAP

Conference

Title
Topical symposium on the behavior and utilization of technetium.
Dates
18-20 Mar 1993.
Place
Sendai (Japan).

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
25030481
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Conference, Numerical Data
Descriptors DEI
ADDUCTS; BOND ANGLE; BOND LENGTHS; EXPERIMENTAL DATA; INFRARED SPECTRA; LATTICE PARAMETERS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; SPACE GROUPS; STRUCTURAL CHEMICAL ANALYSIS; TECHNETIUM COMPOUNDS; TECHNETIUM 99; TRICLINIC LATTICES; X-RAY DIFFRACTION
Descriptors DEC
BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DIFFRACTION; HOURS LIVING RADIOISOTOPES; INFORMATION; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; MAGNETIC RESONANCE; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; RADIOISOTOPES; RESONANCE; SCATTERING; SPECTRA; SYMMETRY GROUPS; TECHNETIUM ISOTOPES; TRANSITION ELEMENT COMPOUNDS; YEARS LIVING RADIOISOTOPES