Published December 14, 1978
| Version v1
Journal article
Three-electron oxidation. XIV. Carbon-13 isotope effect in the three-electron cooxidation of isopropyl alcohol and oxalic acid
Description
Two mechanisms are proposed for the cooxidation of oxalic acid and isopropyl alcohol by chromium(VI). The results of the 13C-isotope effect studies on the mechanism demonstrate the presence of a significant carbon isotope effect. This 13C-isotope effect together with a previously established deuterium isotope effect is taken as providing compelling evidence for the synchronous C--H and C--C bond breaking and thus for a three electron mechanism in the cooxidation reaction
Additional details
Publishing Information
- Journal Title
- J. Phys. Chem.
- Journal Volume
- 82
- Journal Issue
- 25
- Series
- J. Phys. Chem.
- Journal Page Range
- 2751-2752
- ISSN
- 0022-3654
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 10472457
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- No Abstract
- Descriptors DEI
- CARBON 13; CHROMIUM COMPOUNDS; ISOTOPE EFFECTS; OXALIC ACID; OXIDATION; PROPANOLS
- Descriptors DEC
- ALCOHOLS; CARBON ISOTOPES; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; DICARBOXYLIC ACIDS; EVEN-ODD NUCLEI; HYDROXY COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NUCLEI; ORGANIC ACIDS; ORGANIC COMPOUNDS; STABLE ISOTOPES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- Published in summary form only.