Dynamics of the two-spin spin-boson model with a common bath
- 1. Centre for Optical and Electromagnetic Research, Zhejiang Provincial Key Laboratory for Sensing Technologies, Zhejiang University, Hangzhou 310058 (China)
- 2. Division of Materials Science, Nanyang Technological University, Singapore 639798 (Singapore)
Description
Dynamics of the two-spin spin-boson model in the presence of Ohmic and sub-Ohmic baths is investigated by employing a multitude of the Davydov D1 trial states, also known as the multi-D1 Ansatz. Its accuracy in dynamics simulations of the two-spin SBM is improved significantly over the single D1 Ansatz, especially in the weak to moderately strong coupling regime. Validity of the multi-D1 Ansatz for various coupling strengths is also systematically examined by making use of the deviation vector which quantifies how faithfully the trial state obeys the Schrödinger equation. The time evolution of population difference and entanglement has been studied for various initial conditions and coupling strengths. Careful comparisons are carried out between our approach and three other methods, i.e., the time-dependent numerical renormalization group (TD-NRG) approach, the Bloch-Redfield theory, and a method based on a variational master equation. For strong coupling, the multi-D1 trial state yields consistent results as the TD-NRG approach in the Ohmic regime while the two disagree in the sub-Ohmic regime, where the multi-D1 trial state is shown to be more accurate. For weak coupling, the multi-D1 trial state agrees with the two master-equation methods in the presence of both Ohmic and sub-Ohmic baths, but shows considerable differences with the TD-NRG approach in the presence of a sub-Ohmic bath, calling into question the validity of the TD-NRG results at long times in the literature.
Additional details
Identifiers
- DOI
- 10.1063/1.4945390;
Publishing Information
- Journal Title
- Journal of Chemical Physics
- Journal Volume
- 144
- Journal Issue
- 14
- Journal Page Range
- p. 144102-144102.11
- ISSN
- 0021-9606
- CODEN
- JCPSA6
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 49003002
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S97: MATHEMATICAL METHODS AND COMPUTING;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- COUPLING; EXPERIMENTAL DATA; SCHROEDINGER EQUATION; SIMULATION; SPIN; STRONG-COUPLING MODEL; TIME DEPENDENCE; VARIATIONAL METHODS
- Descriptors DEC
- ANGULAR MOMENTUM; CALCULATION METHODS; DATA; DIFFERENTIAL EQUATIONS; EQUATIONS; INFORMATION; MATHEMATICAL MODELS; NUMERICAL DATA; PARTIAL DIFFERENTIAL EQUATIONS; PARTICLE MODELS; PARTICLE PROPERTIES; WAVE EQUATIONS
Optional Information
- Notes
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