Published February 15, 2006
| Version v1
Journal article
Phase evolution of a barium tin 1,2-ethanediolato complex to barium stannate during thermal decomposition
- 1. Fachbereich Chemie, Martin-Luther-Universitaet Halle-Wittenberg, Kurt-Mothes Str. 2, D-06120 Halle (Germany)
- 2. Max-Planck-Institut fuer Mikrostrukturphysik, Weinberg 2, D-06120 Halle (Germany)
Description
The thermal behaviour of [Ba(C2H6O2)4][Sn(C2H4O2)3] used as a BaSnO3 precursor, and its phase evolution during thermal decomposition are described. The initially formed transient barium tin oxycarbonate phase disintegrates into BaCO3 and SnO2, reacting subsequently to BaSnO3. The existence of the intermediate oxycarbonate phase is evidenced by Fourier transformed infrared (FT-IR), X-ray powder diffraction (XRD) and electron energy loss spectroscopy (EELS (ELNES)) investigations
Additional details
Identifiers
- DOI
- 10.1016/j.tca.2005.12.010;
- PII
- S0040-6031(05)00610-6;
Publishing Information
- Journal Title
- Thermochimica Acta
- Journal Volume
- 441
- Journal Issue
- 2
- Journal Page Range
- p. 176-183
- ISSN
- 0040-6031
- CODEN
- THACAS
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 38084506
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETIC ACID; BARIUM CARBONATES; BARIUM COMPLEXES; ENERGY-LOSS SPECTROSCOPY; FOURIER TRANSFORMATION; INFRARED SPECTRA; PYROLYSIS; STANNATES; TIN COMPLEXES; TIN OXIDES; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALINE EARTH METAL COMPLEXES; ALKALINE EARTH METAL COMPOUNDS; BARIUM COMPOUNDS; CARBON COMPOUNDS; CARBONATES; CARBOXYLIC ACIDS; CHALCOGENIDES; CHEMICAL REACTIONS; COHERENT SCATTERING; COMPLEXES; DECOMPOSITION; DIFFRACTION; ELECTRON SPECTROSCOPY; INTEGRAL TRANSFORMATIONS; MONOCARBOXYLIC ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SCATTERING; SPECTRA; SPECTROSCOPY; THERMOCHEMICAL PROCESSES; TIN COMPOUNDS; TRANSFORMATIONS
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.