Published June 2010 | Version v1
Journal article

Ultrasonic velocities, densities, and viscosities of glycylglycine and CoCl2 in aqueous and aqueous ethanol systems at different temperatures

  • 1. Physical Chemistry Division, Department of Chemistry, National Institute of Technology Karnataka Surathkal, Mangalore 575025 (India)

Description

Ultrasonic velocity (u), density (ρ), and viscosity (η) have been measured for glycylglycine and CoCl2 in aqueous and aqueous ethanol systems at T = (288.15 to 318.15) K. Using the experimental values, the adiabatic compressibility (κs), molar hydration number (nH), apparent molar compressibility (KSΦ), apparent molar volume (VΦ), limiting apparent molar compressibility (KSφ0), limiting apparent molar volume (Vφ0), their constants (SK, SV), viscosity coefficients of A and B parameters of Jones-Dole equation, relative viscosity (ηr), and excess Gibbs free energy of activation (ΔG*E) were calculated and the results of all these parameters have been discussed in terms of solute-solvent and solute-solute interactions.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2010.01.010

Additional details

Identifiers

DOI
10.1016/j.jct.2010.01.010;
PII
S0021-9614(10)00011-X;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
42
Journal Issue
6
Journal Page Range
p. 742-751
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.