Published June 2010
| Version v1
Journal article
Ultrasonic velocities, densities, and viscosities of glycylglycine and CoCl2 in aqueous and aqueous ethanol systems at different temperatures
- 1. Physical Chemistry Division, Department of Chemistry, National Institute of Technology Karnataka Surathkal, Mangalore 575025 (India)
Description
Ultrasonic velocity (u), density (ρ), and viscosity (η) have been measured for glycylglycine and CoCl2 in aqueous and aqueous ethanol systems at T = (288.15 to 318.15) K. Using the experimental values, the adiabatic compressibility (κs), molar hydration number (nH), apparent molar compressibility (KSΦ), apparent molar volume (VΦ), limiting apparent molar compressibility (KSφ0), limiting apparent molar volume (Vφ0), their constants (SK, SV), viscosity coefficients of A and B parameters of Jones-Dole equation, relative viscosity (ηr), and excess Gibbs free energy of activation (ΔG*E) were calculated and the results of all these parameters have been discussed in terms of solute-solvent and solute-solute interactions.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2010.01.010Additional details
Identifiers
- DOI
- 10.1016/j.jct.2010.01.010;
- PII
- S0021-9614(10)00011-X;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 42
- Journal Issue
- 6
- Journal Page Range
- p. 742-751
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41076885
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- APPARENT MOLAL VOLUME; COBALT CHLORIDES; COMPRESSIBILITY; DENSITY; EQUATIONS; ETHANOL; FREE ENTHALPY; GLYCYLGLYCINE; HYDRATION; INTERACTIONS; SOLUTES; SOLVENTS; TEMPERATURE RANGE 0273-0400 K; ULTRASONIC WAVES; VELOCITY; VISCOSITY
- Descriptors DEC
- ALCOHOLS; AMINO ACIDS; CARBOXYLIC ACIDS; CHLORIDES; CHLORINE COMPOUNDS; COBALT COMPOUNDS; ENERGY; HALIDES; HALOGEN COMPOUNDS; HYDROXY COMPOUNDS; MECHANICAL PROPERTIES; ORGANIC ACIDS; ORGANIC COMPOUNDS; PEPTIDES; PHYSICAL PROPERTIES; PROTEINS; SOLVATION; SOUND WAVES; TEMPERATURE RANGE; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.