Published November 1999
| Version v1
Journal article
Photodissociation of NaK: Ab initio spin-orbit interaction of the Na (32S) and K (42Pj) manifold
Description
The relevant interstate b3II, A1Σ+, c3Σ+, and B1II spin-orbit induced matrix elements, arising from the Ma (32S) K (42Pj) manifold are treated within the full microscopic Breit-Pauli approximation based on ab initio configuration interaction (CI) wave functions. The determination of these couplings as a function of the internuclear distance of NaK should permit a full treatment of the fine-structure branching ratio K*(42P1/2(D1))/Kasterisk(42P3/2(D2)) in manifold-meditated photodissociation and in the treatment of interstate perturbations
Additional details
Publishing Information
- Journal Title
- International Journal of Quantum Chemistry
- Journal Volume
- 75
- Journal Issue
- 4-5
- Journal Page Range
- p. 693-697
- ISSN
- 0020-7608
- CODEN
- IJQCB2
Conference
- Title
- International Symposium on Atomic, Molecular, and Condensed Matter Theory
- Dates
- 27 Feb - 5 Mar 1999
- Place
- St. Augustine, FL (United States)
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 31014123
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CONFIGURATION INTERACTION; DISSOCIATION; ENERGY LEVELS; FINE STRUCTURE; L-S COUPLING; MATRIX ELEMENTS; POTASSIUM COMPOUNDS; SODIUM COMPOUNDS; WAVE FUNCTIONS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; COUPLING; FUNCTIONS; INTERMEDIATE COUPLING