Published June 15, 1985
| Version v1
Journal article
Kinetics of the reactions of NCO radicals with H2 and NO using laser photolysis--laser induced fluorescence
Creators
- 1. Combustion Research Facility, Sandia National Laboratories, Livermore, California 94550
Description
Absolute rate constants for the reaction of NCO radicals with hydrogen (k6; T = 592--913K) and nitric oxide (k7;T = 294--538K) were measured using excimer laser photolysis-laser induced fluorescence at 416.8 nm. The following Arrhenius expressions summarize the data: k6 = 1.43 x 10-11e/sup() -9000plus-or-minus1500/R/T k7 = 1.69 x 10-11e/sup() 390plus-or-minus320/R/T cm3 molecule-1 s-1. The experimental technique and results are discussed, and the importance of these reactions to combustion chemistry is addressed
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 82
- Journal Issue
- 12
- Series
- J. Chem. Phys.
- Journal Page Range
- 5485-5488
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 16083931
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; COMBUSTION; HYDROGEN; NITRIC OXIDE; NITROGEN COMPOUNDS; RADICALS; REACTION INTERMEDIATES
- Descriptors DEC
- CHALCOGENIDES; CHEMICAL REACTIONS; ELEMENTS; KINETICS; NITROGEN OXIDES; NONMETALS; OXIDATION; OXIDES; OXYGEN COMPOUNDS; REACTION KINETICS