Published 1982 | Version v1
Journal article

Crystal structure of trinitrato-tris-(hexamethylphosphoramide) lanthanum (3)

  • 1. Gruzinskij Politekhnicheskij Inst., Tbilisi (USSR)

Description

X-ray study (diffractometer, lambdaMo, 5500 reflections, isotropic-anisotropic specification, R=0.O78) of compound [La(NO3)3(Hmpa)3]2 is carried out. The crystals are monoclinic: a=16.305 (3), b=11.420(3), c=21.355(5) A, β=93.89(2) deg, Z=2, sp. gr. P21. The structure contains two crystallographically independent types of lanthanum atoms, three-cap trigonal prisms (cn 9) being their coordinational polyhedrons. The values of valent angles and bond lengths are presented

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура тринитрато-трис-(гексаметилфосфорамид)лантана (3)

Publishing Information

Journal Title
Koord. Khim.
Journal Volume
8
Journal Issue
3
Series
Koord. Khim.
Journal Page Range
367-373
ISSN
0132-344X