Published August 2016 | Version v1
Journal article Metadata-only

Magnetic order and electronic properties of Li2Mn2(MoO4)3 material for lithium-ion batteries: ESR and magnetic susceptibility studies

Creators

  • 1. Kazan State Power Engineering University, Kazan (Russian Federation)
  • 2. E. K. Zavoisky Physical-Technical Institute of Russian Academy of Sciences, Kazan (Russian Federation)
  • 3. VIT University, School of Electronics Engineering, Chennai (India)
  • 4. SSN College of Engineering, Department of Chemistry, Chennai (India)
  • 5. Institute of Low Temperature and Structure Research of Polish Academy of Sciences, Wroclaw (Poland)

Description

We describe the application of electron spin resonance (ESR) and magnetic susceptibility methods to study the magnetic properties and valence state of transition metal ions in Li2Mn2(MoO4)3 polyanion compound previously studied for its cathode-active properties in lithium containing batteries. ESR measurements of Li2Mn2(MoO4)3 have shown the presence of Mn2+ ions in the octahedral environment of oxygen ions. It is found that the part of manganese ions occupy the anti-site positions in lithium sublattice. The absence of the ESR signal from molybdenum ions indicates that they are non-magnetic and adopt the 6+ valence state. Considerable overlapping between 3d orbitals of transition metal and 2p oxygen orbitals has been experimentally established. This leads to the indirect exchange interaction and antiferromagnetic ordering of manganese ions at 1.4 K. (orig.)

Availability note (English)

Available from: http://dx.doi.org/10.1007/s00339-016-0278-2

Additional details

Identifiers

DOI
10.1007/s00339-016-0278-2;

Publishing Information

Journal Title
Applied Physics. A, Materials Science and Processing
Journal Volume
122
Journal Issue
8
Journal Page Range
p. 1-6
ISSN
0947-8396
CODEN
APAMFC

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
47117308
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ANTIFERROMAGNETISM; CHARGE STATES; ELECTRON SPIN RESONANCE; EXCHANGE INTERACTIONS; EXPERIMENTAL DATA; LANDE FACTOR; LINE WIDTHS; LITHIUM COMPOUNDS; MAGNETIC SUSCEPTIBILITY; MANGANESE COMPOUNDS; MANGANESE IONS; MOLYBDATES; SPECTRA; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0000-0013 K; TEMPERATURE RANGE 0013-0065 K; TEMPERATURE RANGE 0065-0273 K; TEMPERATURE RANGE 0273-0400 K; VALENCE
Descriptors DEC
ALKALI METAL COMPOUNDS; CHARGED PARTICLES; DATA; DIMENSIONLESS NUMBERS; INFORMATION; INTERACTIONS; IONS; MAGNETIC PROPERTIES; MAGNETIC RESONANCE; MAGNETISM; MOLYBDENUM COMPOUNDS; NUMERICAL DATA; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; REFRACTORY METAL COMPOUNDS; RESONANCE; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS