Published April 1991 | Version v1
Journal article Metadata-only

Phosphorylated adamantanes

Creators

  • 1. Kievskij Politekhnicheskij Inst., Kiev (Ukraine)

Description

Complex formation of alkyl amd adamantyl esters of methylphosphonic acid with trisdipivaloylmethanates (Dpm) of europium and ytterbium was studied, using PMR method. Formation of adducts (1:1 composition), stability constant values of which increase in proportion to accumulation of adamantoxyl groups at phosphorus atom, was determined. Reaction mechanism for Eu(Dpm)3 is presented

Additional details

Additional titles

Subtitle (English)
12. Study of coordinating ability and ligand exchange kinetics of adamantyl esters of methylphosphonic acid in complexes with rare earth dipivaloylmethanates
Original title (Russian)
Фосфорилированные адамантаны
Original subtitle (Russian)
12. Izuchenie koordiniruyushchej sposobnosti i kinetiki ligandnogo obmena adamantilovykh ehfirov metilfosfonovoj kisloty v kompleksakh s dipivaloilmetanatami redkikh zemel'.

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
61
Journal Issue
4
Series
Zh. Obshch. Khim.
Journal Page Range
902-909
ISSN
0044-460X
CODEN
ZOKHA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
23041586
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ADDUCTS; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CYCLOALKANES; KETONES; NMR SPECTRA; PHOSPHONIC ACID ESTERS; PROTONS; RARE EARTH COMPLEXES
Descriptors DEC
ALKANES; BARYONS; CATIONS; CHARGED PARTICLES; COMPLEXES; ELEMENTARY PARTICLES; ESTERS; FERMIONS; HADRONS; HYDROCARBONS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; IONS; KINETICS; NUCLEONS; ORGANIC COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; REACTION KINETICS; SPECTRA; SYNTHESIS