Published November 1995
| Version v1
Journal article
Reaction of alcohols with α-oxides catalized by aluminium and titanium alcoholate complexes of boron trifluoride etherate. 1. Product composition of the reaction
- 1. Moskovskij Khimiko-Tekhnologicheskij Inst., Moscow (Russian Federation)
Description
Products of reaction between primary aliphatic alcohols and ethylene oxide in the presence of catalytic systems on the basis of boron trifluoride etherate and aluminium and titanium alkoxides have been studied, their composition being determined. It is shown that distribution factor for the catalytic system studied is lower than that of previously employed catalysts. Distribution factors of hydroxyethylation products have been calculated. 9 refs., 5 tabs
Additional details
Additional titles
- Original title (Russian)
- Катализ комплексами алкоголятов алюминия и титана с эфиратом трехфтористого бора в реакции спиртов с α-оксидами. 1. Состав продуктов реакции
Publishing Information
- Journal Title
- Kinetika i Kataliz
- Journal Volume
- 36
- Journal Issue
- 6
- Journal Page Range
- p. 857-860.
- ISSN
- 0453-8811
- CODEN
- KNKTA4
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 27043315
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALCOHOLS; ALKOXIDES; ALUMINIUM COMPOUNDS; BORON FLUORIDES; CATALYSTS; CHEMICAL REACTION KINETICS; CONCENTRATION RATIO; ETHERS; TITANIUM COMPOUNDS
- Descriptors DEC
- BORON COMPOUNDS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HYDROXY COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; REACTION KINETICS; TRANSITION ELEMENT COMPOUNDS