Published February 1982
| Version v1
Journal article
Complexes of hydrazine and substituted hydrazines with some oxocations
- 1. Meerut Coll. (India). Dept. of Chemistry
Description
Several new polymeric complexes of general composition MOsub(n)(L)4X2 (where M = V, Zr and U; n = 1 or 2; X = Cl, Br, I, NO3 and NCS and L = N2H4), PhNHNH2 and Me2NNH2 have been synthesised and characterized by elemental and d.t. analyses and by magnetic measurements, electronic and i.r. spectra. The vanadyl(IV) complexes exhibit subnormal magnetic moments (1.26-1.36BM) possibly because of exchange interaction between vanadium(IV) ions. The thermal stability of hydrazine complexes fall in the order: Cl > Br > NCS > I. The M-N bond strength, as revealed, by ν(M-N), decreases as: Me2NNH2 > N2H4 > PhNHNH2. (orig.)
Additional details
Publishing Information
- Journal Title
- Transition Met. Chem.
- Journal Volume
- 7
- Journal Issue
- 1
- Series
- Transition Met. Chem.
- Journal Page Range
- 41-44
- ISSN
- 0340-4285
Conference
- Title
- Symposium on frontiers of coordination chemistry.
- Dates
- 6 - 8 Dec 1979.
- Place
- Allahabad, India.
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- Germany
- INIS RN
- 13688639
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CHEMICAL ANALYSIS; CHEMICAL PREPARATION; DIFFERENTIAL THERMAL ANALYSIS; ELECTRONIC STRUCTURE; HYDRAZINE; INFRARED SPECTRA; MAGNETIC MOMENTS; URANYL COMPLEXES; VANADIUM COMPLEXES; ZIRCONIUM COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; COMPLEXES; SPECTRA; SYNTHESIS; THERMAL ANALYSIS; TRANSITION ELEMENT COMPLEXES; URANIUM COMPLEXES