Published April 4, 1973 | Version v1
Journal article Metadata-only

Exchange with deuterium and isomerization of some alkenes catalysed by gallium oxide

Creators

  • 1. Queen's Univ., Belfast, Northern Ireland (UK). Dept. of Chemistry

Description

Gallium oxide catalyses with high selectivity the exchange with deuterium of vinylic and allylic hydrogens in a variety of alkenes, and directly interconverts cis and trans isomers of butenes and pentenes at temperatures well below those required for double-bond shift.

Additional details

Identifiers

DOI
10.1039/c39730000231;

Publishing Information

Journal Title
Journal of the Chemical Society, Chemical Communications
Journal Issue
7
Series
J. Chem. Soc. (London), Chem. Commun.
Journal Page Range
231
ISSN
0022-4936

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
4067786
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BINDING ENERGY; BUTENES; CATALYSIS; CATALYSTS; CHEMICAL BONDS; CHEMICAL REACTIONS; DEUTERIUM; DEUTERIUM COMPOUNDS; DOUBLE BONDS; GALLIUM OXIDES; HYDROGEN; ISOMERS; ISOTOPE EFFECTS; ISOTOPIC EXCHANGE; LABELLED COMPOUNDS; PENTENES; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE; TRACER TECHNIQUES
Descriptors DEC
ALKENES; CHALCOGENIDES; ELEMENTS; ENERGY; GALLIUM COMPOUNDS; HYDROCARBONS; HYDROGEN ISOTOPES; ISOTOPE APPLICATIONS; ISOTOPES; LIGHT NUCLEI; NONMETALS; NUCLEI; ORGANIC COMPOUNDS; OXIDES; STABLE ISOTOPES

Optional Information

Notes
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