Published October 2003
| Version v1
Journal article
Structural chemistry and magnetic properties of La2LiRuO6
Description
A combination of magnetometry, electron microscopy, neutron diffraction and 7Li MASNMR spectroscopy has been used to determine that La2LiRuO6 has a monoclinic perovskite-related structure (space group P21/n, a=5.5555(2), b=5.5977(2), c=7.8454(3) A, β=90.020(5) deg. at 300 K) with a 1:1 ordered arrangement of Li+ and Ru5+ cations occupying the six-coordinate sites. The compound is antiferromagnetic (type I) below 30 K with an ordered magnetic moment of 2.2(2) μB per Ru. The magnetic properties of this phase are compared with those of Sr3LiRuO6 and Ca3LiRuO6
Additional details
Identifiers
- DOI
- 10.1016/S0022-4596(03)00081-1;
- arXiv
- arXiv:nlin/0301022v1;
- PII
- S0022459603000811;
Publishing Information
- Journal Title
- Journal of Solid State Chemistry
- Journal Volume
- 175
- Journal Issue
- 1
- Journal Page Range
- p. 20-26
- ISSN
- 0022-4596
- CODEN
- JSSCBI
Conference
- Title
- ACS symposium on metal oxides
- Dates
- 18-22 Aug 2002
- Place
- Boston, MA (United States)
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 35037932
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ANTIFERROMAGNETISM; CALCIUM OXIDES; ELECTRON MICROSCOPY; LANTHANUM OXIDES; LITHIUM IONS; LITHIUM OXIDES; MAGNETIC MOMENTS; MAGNETIC PROPERTIES; MONOCLINIC LATTICES; NEUTRON DIFFRACTION; NMR SPECTRA; RUTHENIUM IONS; RUTHENIUM OXIDES; STRONTIUM OXIDES; TEMPERATURE RANGE 0013-0065 K
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; CALCIUM COMPOUNDS; CHALCOGENIDES; CHARGED PARTICLES; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; IONS; LANTHANUM COMPOUNDS; LITHIUM COMPOUNDS; MAGNETISM; MICROSCOPY; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; RARE EARTH COMPOUNDS; REFRACTORY METAL COMPOUNDS; RUTHENIUM COMPOUNDS; SCATTERING; SPECTRA; STRONTIUM COMPOUNDS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.