Published June 2005 | Version v1
Journal article Metadata-only

Electrochemical oxidation of iodide in the presence of benzenesulfinic acids and Its application to the quasi-catalytic determination of benzenesulfinic acids

Creators

  • 1. Univ. v Bu-Ali-Sina, Fakul'tet Nauk, Khamadan (Iran, Islamic Republic of)

Description

The mechanism of the electrochemical oxidation of iodide in the presence of 4-toluenesulfinic acid was studied in an aqueous solution using cyclic voltammetry and controlled-potential coulometry. The results indicate that the anodically generated iodine reacts with 4-toluenesulfinic acid through a quasi-catalytic process. In addition, the results indicate the suitability of iodide as a mediator for the determination of 4-toluene-sulfinic acid in aqueous solutions. The quasi-catalytic peak currents are linearly dependent on the 4-toluene-sulfinic acid concentrations in the range 6.0 x 10-3 - 8.0 x 10-6 M

Abstract (Russian)

Исследован механизм электрохимического окисления иодида в присутствии 4-толуолсульфиновой кислоты (4-ТСФК) в водных растворах с использованием циклической вольтамперометрии и кулонометрии при контролируемом потенциале. Найдено, что образующийся на аноде иод реагирует с 4-ТСФК по механизму квазикаталитического процесса и иодид может служить в качестве медиатора при определении 4-ТСФК в водных растворах. Квазикаталитический ток линейно зависит от концентрации 4-ТСФК в интервале 6.0 х 10-3 - 8.0 x 10-6 М

Additional details

Additional titles

Original title (Russian)
Электрохимическое окисление иодида в присутствии бензолсульфиновых кислот. Применение для определения бензолсульфиновых кислот

Publishing Information

Journal Title
Zhurnal Analiticheskoj Khimii
Journal Volume
60
Journal Issue
6
Journal Page Range
p. 598-602
ISSN
0044-4502
CODEN
ZAKHA8

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36106693
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; AROMATICS; CHEMICAL REACTION KINETICS; ELECTROCHEMISTRY; ELECTROLYSIS; IODIDES; ORGANIC ACIDS; ORGANIC SULFUR COMPOUNDS; OXIDATION; VOLTAMETRY
Descriptors DEC
CHEMICAL REACTIONS; CHEMISTRY; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; IODINE COMPOUNDS; KINETICS; LYSIS; MIXTURES; ORGANIC COMPOUNDS; REACTION KINETICS; SOLUTIONS

Optional Information

Notes
22 refs., 6 figs.