Published January 1976
| Version v1
Journal article
Schiff base complexes of dioxouranium(VI). Pt. 2
Description
Dioxouranium(VI) derivatives of the type UO2(NO3)2(SBH2)2 have been synthesised by the reactions of dioxouranium(VI) nitrate hexahydrate with the nitrogen donor ligands (SBH2) in 1 : 2 molar ratio. The Schiff bases used in these reactions are of the general type, o-HOC6H4C(CH3): NX1OH (where X1 = -CH2CH2-, -CH2CH(CH3)- and -CH2CH2CH2-), CH3C(OH)CHC(CH3): NX2OH and o-OHC6H4CH: NX2OH (where X2 = -CH2CH2-, -CH2CH(CH3)-, -CH2CH2CH2- and o-C6H4). The resulting new derivatives have been characterized on the basis of elemental analysis, magnetic susceptibility, conductance measurements and infrared spectra. (orig.)
Abstract (German)
Dioxouran(VI) Derivate des Typs UO2(NO3)2(SBH2)2 wurden durch Reaktion von Dioxouran(VI) nitrathexahydrat mit den Stickstoffdonorliganden (SBH2) im Molarverhaeltnis 1:2 synthetisiert. Die verwendeten Schiffschen Basen entsprechen dem allgemeinen Typ, d.h. o-HOC6H4C(CH3) : NX1OH (wobei X1 = -CH2CH2-, -CH2CH(CH3)- und -CH2CH2CH2-), CH3C(OH)CHC(CH3): NX2OH und o-OHC6H4CH: NX2OH (wobei X2 = -CH2CH2-, -CH2CH(CH3)-, -CH2CH2CH2- und oC6H4). Die neuen Derivate wurden aufgrund von Elementanalyse, magnetischer Suszeptibilitaet, Messungen der Leitfaehigkeit und Infrarotspektren charakterisiert. (orig./AK)Additional details
Additional titles
- Subtitle (English)
- Dioxouranium(VI) complexes of the Schiff bases of o-hydroxy acetophenone, 2,4-pentandione and salicylaldehyde
Identifiers
Publishing Information
- Journal Title
- Zeitschrift für Naturforschung B
- Journal Volume
- 31
- Journal Issue
- 1
- Series
- Z. Naturforsch., B.
- Journal Page Range
- 22-28
- ISSN
- 1865-7117
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 7257209
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; DATA; ELECTRIC CONDUCTIVITY; HYDRATES; INFRARED SPECTRA; LIGANDS; MAGNETIC SUSCEPTIBILITY; SCHIFF BASES; TABLES; URANIUM COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; COMPLEXES; ELECTRICAL PROPERTIES; IMINES; INFORMATION; MAGNETIC PROPERTIES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS
Optional Information
- Notes
- 2 figs.; 5 tabs.; 18 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent